Non-Halogenated-Solvent Processed and Additive-Free Tandem Organic Solar Cell with Efficiency Reaching 16.67%

Organic solar cells (OSCs) have recently reached a remarkably high efficiency and become a promising technology for commercial application. However, OSCs with top efficiency are mostly processed by halogenated solvents and with additives that are not environmentally friendly, which hinders large-scale manufacture. In this study, high-performance tandem OSCs, based on polymer donors and two small-molecule acceptors with different bandgaps, are fabricated by solution processing with non-halogenated solvents without additive. Importantly, the two active layers developed from non-halogenated solvents show better phase segregation and charge transport properties, leading to superior performance than halogenated ones. As a result, a tandem OSC with high efficiency of up to 16.67% is obtained, showing unique advantages in future massive production.     

Metal chlorides-promoted ammonia absorption of deep eutectic solvent

Ammonia is considered as a promising hydrogen or energy carrier. Ammonia absorption or adsorption is an important aspect for both ammonia removal, storage and separation applications. To these ends, a wide range of solid and liquid sorbents have been investigated. Among these, the deep eutectic solvent (DES) is emerging as a promising class of ammonia absorbers. Herein, we report a novel type of DES, i.e., metal-containing DESs for ammonia absorption. Specifically, the NH₃ absorption capacity is enhanced by ca. 18.1–36.9% when a small amount of metal chlorides, such as MgCl₂, MnCl₂ etc., are added into a DES composed of resorcinol (Res) and ethylene glycol (EG). To our knowledge, the MgCl₂/Res/EG (0.1:1:2) DES outperforms most of the reported DESs. The excellent NH₃ absorption performances of metal–containing DESs have been attributed to the synergy of Lewis acid–base and hydrogen bonding interactions. Additionally, good reversibility and high NH₃/CO₂ selectivity are achieved over the MgCl₂/Res/EG (0.1:1:2) DES, which enables it to be a potential NH₃ absorber for further investigations.     

Comparison of 3-breed rotational crossbreds of Montbéliarde,Viking Red,and Holstein with Holstein cows fed 2 alternative diets for dry matter intake,production, and residual feed intake

The objective of this study was to compare 3-breed rotational crossbred (CB) cows of the Montbéliarde, Viking Red, and Holstein (HO) breeds with HO cows fed 2 alternative diets for dry matter intake (DMI), fat plus protein production (CFP), body weight (BW), body condition score (BCS), feed efficiency, and residual feed intake (RFI) from 46 to 150 days in milk (DIM) during first lactation. The CB cows (n = 17) and HO cows (n = 19) calved from September 2019 to March 2020. Cows were fed either a traditional total mixed ration diet (TRAD) or a higher fiber, lower starch total mixed ration diet (HFLS). The HFLS had 21% more corn silage, 47% more alfalfa hay, 44% less corn grain, and 43% less corn gluten feed than the TRAD. The 2 diets were analyzed for dry matter content, crude protein, forage digestibility, starch, and net energy for lactation. The BW and BCS were recorded once weekly. Daily milk, fat, and protein production were estimated from twice monthly milk recording with random regression. Measures of efficiency were CFP per kilogram of DMI and DMI per kilogram of BW. The RFI from 46 to 150 DIM was the residual error from regression of DMI on milk energy, metabolic BW, and the energy required for change in BW. Statistical analysis of all variables included the fixed effects of diet, breed group, and the interaction of diet and breed group. The CB cows fed HFLS had less DMI (?12%) and lower DMI/BW (?14%) compared with the HO cows fed TRAD. For CFP, CB and HO cows were not different when fed TRAD or HFLS. Furthermore, the CB cows fed HFLS had higher BW (+50 kg) compared with HO cows fed HFLS. The CB cows fed TRAD had higher BCS than HO cows fed TRAD and HO cows fed HFLS (+0.46 and +0.62, respectively). The HO cows fed TRAD had more DMI (+14%) and lower CFP per kilogram of DMI (?12%) compared with the HO cows fed HFLS. In addition, mean RFI from 46 to 150 DIM was lower and more desirable for CB cows fed HFLS (?120.0 kg) compared with HO cows fed TRAD (85.3 kg). Dairy producers may feed either TRAD or HFLS to CB cows without loss of CFP.     

No-reference quality assessment of dynamic sports videos based on a spatiotemporal motion model

This paper proposes an approach to improve the performance of no-reference video quality assessment for sports videos with dynamic motion scenes using an efficient spatiotemporal model. In the proposed method, we divide the video sequences into video blocks and apply a 3D shearlet transform that can efficiently extract primary spatiotemporal features to capture dynamic natural motion scene statistics from the incoming video blocks. The concatenation of a deep residual bidirectional gated recurrent neural network and logistic regression is used to learn the spatiotemporal correlation more robustly and predict the perceptual quality score. In addition, conditional video block-wise constraints are incorporated into the objective function to improve quality estimation performance for the entire video. The experimental results show that the proposed method extracts spatiotemporal motion information more effectively and predicts the video quality with higher accuracy than the conventional no-reference video quality assessment methods.     

核磁共振方法研究油水过渡带驱替特征

目前,利用常规手段难以对低含油饱和度油水过渡带进行开采,利用气驱及化学驱方式开采仍具有开发潜力,但对于不同类型的油水过渡带,其开发机理不明确。开展4组天然岩心驱替实验,利用核磁共振技术研究不同类型油水过渡带中剩余油的启动机理和主要分布状态,在此基础上研究油水过渡带的开发特征。实验结果表明,气驱开发方式更适用于低渗岩心;化学驱的乳化及降低表面张力作用对小孔隙中剩余油有较好的动用程度,提高采收率效果显著。     

基于深度学习的彩色以及近红外图像去马赛克

单传感器捕获的彩色-近红外（RGB-NIR）图像存在光谱干扰，从而导致重建出的标准彩色图像（RGB）图像与近红外（NIR）图像存在色彩失真以及细节信息模糊。针对这个问题提出一种基于深度学习的去马赛克方法，通过引入跳远连接与稠密连接解决了梯度消失和梯度弥散问题，使得网络更容易训练，并且提升了网络的拟合能力。首先，用浅层特征提取层提取了马赛克图像的像素相关性以及通道相关性等低级特征；然后，将得到的浅层特征图输入到连续多个的残差稠密块以提取专门针对去马赛克的高级语义特征；其次，为充分利用低级特征与高级特征，将多个残差稠密块提取到的特征进行组合；最后，通过全局跳远连接恢复最终的RGB-NIR图像。在深度学习框架Tensorflow上使用公共的图像与视觉表示组（IVRG）数据集、有植被的户外多光谱图像（OMSIV）数据集和森林（Forest）三个公开数据集进行实验。实验结果表明，所提方法优于基于多级自适应残差插值、基于卷积卷积和神经神经网络以及基于深度残差U型网络的主流的RGB-NIR图像去马赛克方法。     

二次侧非能动余热排出系统流动不稳定性研究

二次侧非能动余热排出（ASP）系统是压水堆核电厂应对全厂断电事故的重要措施之一。为研究ASP系统的运行特性，设计建造了ASP系统试验装置（ASPTF）。在ASPTF上开展了ASP系统运行稳定性影响试验，并对试验结果进行了理论分析。试验研究与理论分析结果表明：低压低功率下ASP系统中出现流动不稳定性；增加蒸汽管线或回水管线阻力系数可抑制ASP系统出现流动不稳定性；降低加热功率时ASP系统更易出现流动不稳定性；主泵运行状态影响ASP系统的输入功率进而影响系统的流动不稳定性。     

利用热解-气相色谱/质谱联用仪研究减压渣油及其胶质亚组分的热解规律

以长庆减压渣油及其胶质亚组分为原料，利用热解-气相色谱/质谱联用仪对其在不同条件下热解的产物进行分析，考察反应温度和升温速率对减压渣油热解的影响。结果表明：随着反应温度升高，热解产物中低碳烯烃含量增加，汽柴油馏分含量先增加后减小，在700 ℃ 时达到峰值；升温速率为1℃/ms时，汽柴油馏分含量最高；芳碳率越大、缩合程度越高的重胶质裂解能力越差。     

镓锗铜萃余液综合利用研究与应用

本文针对镓锗铜综合回收系统产出的萃余液,设计通过中和氧化除杂、锌粉置换除铜镉、有机试剂除钴镍、纯碱法生产碱式碳酸锌、高温煅烧生产活性氧化锌和一步法生产元明粉的生产工艺流程,有效的将镓锗铜萃余液分类分离富集,产出具有价值的富集渣和工业产品,进一步提升综合回收经济效益。